Highlander: The Series - Season 1 Episode 12 Eyewitness

Tessa witnesses the murder of a painter, Anne Wheeler, but the absence of a body leads everyone but MacLeod to doubt her story. MacLeod supports Tessa in her quest to obtain justice for Anne. It develops that Anne was killed by her Immortal ex-lover, to keep her from revealing his secret. After Tessa is taken to a police safe house, MacLeod realizes that the killer is in fact the Chief of Detectives, and he must rescue Tessa and bring justice to Anne's killer.